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How
to Configure Outlook 2003 for SMTP Authentication
Just follow
the steps below:
On the Toolbar, click Tools and select E-mail Accounts from the
menu.

The
E-mail Accounts window opens.
Select
View or change existing e-mail accounts.
Click
Next to continue.
Select
POP3 from the list of options.
Click
Next to continue.
Select the email account you wish to change, and select the change button

Click
the More Settings button.

Select
the Outgoing Server tab. 
Enabling
SMTP authentication:Outgoing
Server tab:
Check
the box My outgoing server (SMTP) requires authentication and check the filed that says u se same settings as my incoming mail server.
Click OK.

Congratulations!
You have successfully configured Outlook 2003 for SMTP Authentication.
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